|
KMID : 1059519950390100769
|
|
Journal of the Korean Chemical Society
1995 Volume.39 No. 10 p.769 ~ p.775
|
|
|
Shock Tube Study on the Reaction of Methyl Radical with Molecular Oxygen
|
|
Shin Kuan-Su
|
|
|
Abstract
|
|
|
|
The reaction between CH3 radicals and O2 was investigated in incident shock waves at temperatures between 1390 and 2250 K and densities from 1.5 to 5.3 mol/m+30/3 using azomethane as a source of methyl radicals by following the consumption of CH3 radicals with time resolved UV absorption measurements at 213.9 nm. The rate constant expression k2=1.35 × 1012 exp( - 5900 K/T) cm3 mol-1s-1 for the reaction of CH3 + O2 → CH2O + OH was derived.
|
|
|
KEYWORD
|
|
|
|
|
|
FullTexts / Linksout information
|
|
|
|
|
|
Listed journal information
|
|
|